Spectroscopic constants and potential energy curves of some iodine valence ungerade weakly bound states
نویسندگان
چکیده
منابع مشابه
Ab initio potential energy curves of the valence, Rydberg, and ion-pair states of iodine monochloride, ICl.
We present for the first time a coherent ab initio study of 39 states of valence, Rydberg, and ion-pair character of the diatomic interhalogen ICl species through large scale multireference variational methods including spin-orbit effects coupled with quantitative basis sets. Various avoided crossings are responsible for a non-adiabatic behaviour creating a wonderful vista for its theoretical d...
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Structured emission in the gas phase to two weakly bound valence states that correlate with the third dissociation limit, I*(2P1/2)+I*(2P1/2), designated as (bb), from two third tier ion-pair states of I2 correlating with I-(1S0)+I+(1D2), the 1g(1D2), and F'0u+(1D2) states, has been observed for the first time. The 1u(bb) state is shown to be bound by 377+/-2 cm(-1) and molecular constants have...
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ژورنال
عنوان ژورنال: Journal of Physics B: Atomic, Molecular and Optical Physics
سال: 2015
ISSN: 0953-4075,1361-6455
DOI: 10.1088/0953-4075/48/5/055101